Australian Journal of Chemistry

The Effect of Steric Hindrance on Radical and Ionic Substitution Reactions of Nucleophiles with Some α-Alkyl-p-Nitrobenzyl Chlorides

RK Norris, D Randles

文献索引：Norris,R.K.; Randles,D. Australian Journal of Chemistry, 1979 , vol. 32, p. 1487 - 1509

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被引用次数: 17

摘要

Abstract The reactions of the α-alkyl p-nitrobenzyl chlorides, p-NO 2 C 6 H 4 CH (CI) R (R= Me, Pr 1, Bu t), with nucleophiles, eg, nitrite, nitroethanide, benzenethiolate and p- toluenesulfinate ions and the anion derived from diethyl 2-methylmalonate, in dimethyl sulfoxide have been studied. When R= Bu t, S RN l reactions take place and give, in the reaction with p-toluenesulfinate and the anion from diethyl 2-methylmalonate, extremely ...