Synthesis

Cobalt (I)-catalyzed stereoselective olefination of alkylzinc reagents with aldehydes

JX Wang, Y Fu, Y Hu, K Wang

文献索引：Wang, Jin-Xian; Fu, Ying; Hu, Yulai; Wang, Kehu Synthesis, 2003 , # 10 p. 1506 - 1510

全文：HTML全文

被引用次数: 15

摘要

The reaction of alkylzinc reagents and carbonyl compounds represents one of the most reliable methods to prepare optically active secondary alcohols. [7] [8] In addition, we have also reported that the substitution reaction of nitro group [9] and dialkylation reaction [10] of alkylzinc reagents using [Ni(acac) 2 ] as a catalyst in the presence of a tertiary amine and silylating agent. Recently, we have reported the stereoselective synthese of (E)-stilbenes [11] by the ...