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One??pot synthesis of polyrotaxane by clipping and cyclopolymerization of α, ω??diethynyl isophthalamide with pyridiniumdicarboxamide chloride

T Isono, T Satoh, T Kakuchi

文献索引:Isono, Takuya; Satoh, Toshifumi; Kakuchi, Toyoji Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 14 p. 3184 - 3192

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被引用次数: 7

摘要

Abstract The one-pot synthesis of a main chain-type polyrotaxane composed of axle molecules threaded through the macrocyclic units on the polymer main chain was achieved via the combination of cyclopolymerization and clipping procedures. The cyclopolymerization of an α, ω-diethynyl monomer bearing an isophthalamide moiety (1), which clips onto an axle component bearing a pyridiniumdicarboxamide moiety (2· Cl) ...