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The Journal of Organic Chemistry

Diphenylcarbinyl Derivatives. I. Solvolysis of some Monosubstituted Benzhydryl Chlorides

S Nishida

文献索引:Nishida,S. Journal of Organic Chemistry, 1967 , vol. 32, p. 2692 - 2695

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被引用次数: 56

摘要

Most benzhydrols are prepared by the sodium borohydride reduction of corresponding benzophenones; chlorides are prepared by the reaction of carbinols with hydrogen chloride. Dry hydrogen chloride is introduced into a solution of benzhydrol in purified methylene dichloride in the presence of Drierite; after drying the solution by the addition of fresh Drierite, the solvent is removed under the reduced pressure. In this manner, benzhydryl ...