Dalton Transactions

Organotrichlorogermane synthesis by the reaction of elemental germanium, tetrachlorogermane and organic chloride via dichlorogermylene intermediate

M Okamoto, T Asano, E Suzuki

文献索引：Okamoto, Masaki; Asano, Takuya; Suzuki, Eiichi Dalton Transactions, 2004 , # 15 p. 2372 - 2376

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被引用次数: 2

摘要

Organotrichlorogermanes were synthesized by the reaction of elemental germanium, tetrachlorogermane and organic chlorides, methyl, propyl, isopropyl and allyl chlorides. Dichlorogermylene formed by the reaction of elemental germanium with tetrachlorogermane was the reaction intermediate, which was inserted into the carbon–chlorine bond of the organic chloride to give organotrichlorogermane. When isopropyl or allyl chloride was ...