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Tetrahedron Letters

A chemoselective desulfurization method via homogeneous nickel catalysis

BM Trost, PL Ornstein

文献索引:Trost, Barry M.; Ornstein, Paul L. Tetrahedron Letters, 1981 , vol. 22, # 36 p. 3463 - 3466

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被引用次数: 50

摘要

Abstract Isopropylmagnesium bromide in the presence of bis-(triphenylphosphino)-nickel (II) chloride reduces vinyl sulfides stereospecifically to the corresponding olefins without overreduction-a process which serves as a key step in the synthesis of the sex pheromone of the Douglas fir tussock moth.