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Chiral dipole-stabilized anions: experiment and theory in benzylic and allylic systems. Stereoselective deprotonations, pyramidal inversions, and stereoselective …

K Rein, M Goicoechea-Pappas…

文献索引:Journal of the American Chemical Society, , vol. 111, # 6 p. 2211 - 2217

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被引用次数: 73

摘要

... The high yields and stereoselectivities of this sequence have prompted us to undertake an extensive investigation of ... orbital calcula- tions, we offer a mechanism that is consistent with the chemistry of chiral ... 0002-7863/89/1511-2211$01.50/0 0 1989 American Chemical Society ...