Cesium Carbonate Mediated Borylation of Aryl Iodides with Diboron in Methanol

J Zhang, HH Wu, J Zhang

文献索引：Zhang, Jieming; Wu, Hai-Hong; Zhang, Junliang European Journal of Organic Chemistry, 2013 , # 28 p. 6263 - 6266

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被引用次数: 12

摘要

Abstract Herein we describe the unexpected borylation of aryl iodides promoted by a Cs 2 CO 3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.