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Direct Conversion of Arylamines to Pinacol Boronates: A Metal??Free Borylation Process

…, Y Jiang, D Qiu, Y Zhang, J Wang

文献索引:Mo, Fanyang; Jiang, Yubo; Qiu, Di; Zhang, Yan; Wang, Jianbo Angewandte Chemie - International Edition, 2010 , vol. 49, # 10 p. 1846 - 1849

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被引用次数: 107

摘要

Arylboronic acids or arylboronates have found widespread applications in transition-metal- catalyzed CÀC bond forming reactions, as represented by the Suzuki–Miyaura crosscoupling reaction.[1] These applications have created an increasing demand for various boronic acids and esters.[2] The most commonly utilized method to prepare these boron compounds is the reaction of aryl Grignard reagents or aryllithium reagents with ...