Sulfamic acid/methanol was found to be an efficient catalytic system for the synthesis of benzimidazole compounds through the condensation of o-phenylenediamine with orthoester in high yields at room temperature. ... Keywords. Benzimidazole; o-Phenylenediamines; Orthoesters; Sulfamic acid/methanol system; Synthesis. ... Keywords. Benzimidazole; o-Phenylenediamines; Orthoesters; Sulfamic acid/methanol system; Synthesis. ... To view the rest of this content ...