Mechanistic implications of pyrophosphate formation in the oxidation of O, S-dimethyl phosphoramidothioate

DR Leslie, WT Beaudry, LL Szafraniec…

文献索引：Leslie, D. Ralph; Beaudry, William T.; Szafraniec, Linda L.; Rohrbaugh, Dennis K. Journal of Organic Chemistry, 1991 , vol. 56, # 10 p. 3459 - 3462

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被引用次数: 8

摘要

(9) The* lP chemical shift for 9, presumed to have formed (although no supporting evidence for ita presence was reported), in the 3-chloroperbenzoic acid oxidation of 7 haa previously been reported aa a single line at 6-6.53 or 6-6.74 (ref 3). In our hands, oxidation of 7 with 3- chloroperbenzoic acid resulted in a mixture of producta, including 9. The chemical shifta of diastereomeric 9 in this reaction solution were 6 1.6 and 6 1.2.