Journal of the American Chemical Society

A Study of n-Octadecenoic Acids. I. Synthesis of cis-and trans-7-through 12-and of 17-Octadecenoic Acids1

WF Huber

文献索引：Huber Journal of the American Chemical Society, 1951 , vol. 73, p. 2730,2731

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被引用次数: 83

摘要

As the h-st step in a systematic study of the more important n-octadecenoic acids, the cis isomers of 7-through 12-octadecenoic acids were prepared by partial hydrogenation of the corresponding synthetic octadecynoic acids. Isomerization of the cis acids in the presence of selenium yielded the trans forms. 17-Octadecenoic acid was obtained by condensing the Grignard reagent of 10-undecenyl bromide with 6-carbethoxycaproyl chloride to form ethyl ...