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Photolytic rearrangement and halogen-dependent photocylization of halophenylnaphthalenes. II

WA Henderson Jr, R Lopresti…

文献索引:Henderson,W.A. et al. Journal of the American Chemical Society, 1969 , vol. 91, # 22 p. 6049 - 6057

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被引用次数: 24

摘要

Abstract: Photolysis of 1-(o-chloropheny1) naphthalene proceeds with unusual efficiency to give a high yield of fluoranthene under a wide variety of conditions, while 1-(o4odophenyl) naphthalene gives a variety of rearrangement and solvolytic products but virtually no fluoranthene. The bromo derivative exhibits intermediate behavior. The above chloro compound produces fluoranthene in somewhat better yield and quantum yield in more ...