The Journal of organic chemistry

Stereoselective Synthesis of (Z)-and (E)-Allylic Silanes by Copper-Mediated Substitution Reactions of Allylic Carbamates with Grignard Reagents

JH Smitrovich, KA Woerpel

文献索引：Suginome, Michinori; Iwanami, Taisuke; Matsumoto, Akira; Yoshihiko, Ito Tetrahedron Asymmetry, 1997 , vol. 8, # 6 p. 859 - 862

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被引用次数: 54

摘要

... Volume: Page: ... We also felt that this transformation would provide valuable insight into the mechanism of copper-mediated allylic displacement reactions. ... 38,39 of acetate 17 with dicyclohexylborane 38 and protonolysis with acetic acid (eq 8). 40 Deprotection of ...