Polystyrene and polymethacrylate resin-supported Jacobsen's alkene epoxidation catalyst
L Canali, E Cowan, H Deleuze, CL Gibson…
文献索引：Canali, Laetitia; Cowan, Elaine; Deleuze, Herve; Gibson, Colin L.; Sherrington, David C. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 13 p. 2055 - 2066
Polystyrene and polymethacrylate-based resin supported Jacobsen's chiral Mn salen complexes have been prepared. The resins are of defined molecular structure and morphology, and the complexes have been attached primarily in a pendant fashion. The loadings of Mn (III) are in the range≈ 0.08–0.35 mmol g− 1 to maximise the likelihood of site- isolation. The polymer-supported complexes have been used as enantioselective ...
