Salts and Ionic Liquids of Resonance Stabilized Amides

H Brand, J Martens, P Mayer, A Schulz…

文献索引：Brand, Harald; Martens, Joern; Mayer, Peter; Schulz, Axel; Seibald, Markus; Soller, Thomas Chemistry - An Asian Journal, 2009 , vol. 4, # 10 p. 1588 - 1603

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被引用次数: 3

摘要

Abstract The synthesis, structure, and bonding of alkali salts of resonance stabilized amides, such as diformylamide (dfa), formylcyanoamide (fca), nitrocyanoamide (nca), and for comparision, the well-known dicyanoamide (dca), are discussed on the basis of experimental and theoretical data. The first structural reports of K (18-crown-6)+ dfa−, K (18- crown-6)+ fca−, Na+ nca−, and Li (TMEDA)+ dca− are presented. Examination of the X-ray ...