RuIII (OTf) SalophenCH2–NHSiO2–Fe: an efficient and magnetically recoverable catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane
Efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) catalyzed by ruthenium (III) complex of chloromethylated Salophen supported on nanomagnetic materials is reported. First, the iron nanomagnets were silica coated, functionalized with amine and then ruthenium CM-Salophen was successfully bonded to their surface. The catalyst, RuIII (OTf) SalophenCH2–NHSiO2–Fe, was characterized by ...