Chemistry of organosilicon compounds: LXXXVIII. Mass spectroscopy of organosilicon compounds. Part 2. Methoxymethyldisilanes

Y Nakadaira, T Kobayashi, M Kira, H Sakurai…

文献索引：Nakadaira,Y. et al. Journal of Organometallic Chemistry, 1976 , vol. 113, p. 249 - 256

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被引用次数: 12

摘要

Abstract Mass spectra of various methoxymethyldisilanes were examined in detail. Characteristic features of the spectra of these compounds are:(a) the fission of the Si—C bond occurs more readily than that of the Si Si bond;(b) the methoxy group is eliminated as formaldehyde;(c) the silicon analog of an acyl cation is formed from the [M 15]+ ion;(d) the 1, 2-shift of the methoxy group is characteristic in the fragmentation process.