Journal of Catalysis

Heterogeneously catalyzed asymmetric hydrogenation of α-arylenamides over immobilized RhBPE and RhDUPHOS complexes

A Crosman, WF Hoelderich

文献索引：Crosman, Adrian; Hoelderich, Wolfgang F. Journal of Catalysis, 2009 , vol. 265, # 2 p. 229 - 237

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被引用次数: 11

摘要

Optically active α-1-arylalkylamine derivatives were successfully synthesized through heterogeneous asymmetric hydrogenation of α-arylenamides over immobilized RhBPE and RhDUPHOS complexes on aluminum-containing M41S and SBA-15 type materials. The heterogeneous chiral catalysts were prepared by immobilization of rhodium diphosphine complexes on Al-MCM-41, Al-MCM-48, and Al-SBA-15. The complexes were bonded to ...