In situ cuprate formation via transmetalation between vinylstannanes and higher order cyanocuprates

…, JS Ng, AL Campbell, R Moretti…

文献索引：Behling, James R.; Babiak, Kevin A.; Ng, John S.; Campbell, Arthur L.; Moretti, Robert; et al. Journal of the American Chemical Society, 1988 , vol. 110, # 8 p. 2641 - 2643

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被引用次数: 176

摘要

J. Am. Chem. SOC. 1975, 97, 107.(1 1)(a) The choice of Me2Cu (CN) Liz for the in situ generation of vinyl cuprates was based upon the optimization of results obtained for misoprostol (5). However, the following cuprates have also been shown to undergo in situ ligand exchange with vinylstannanes: Me (Bu) Cu (CN) Liz.'b Bu2Cu (CN) Li2,* M~(~-T~) CU (CN) L~,,~ I~ B u (~-T~) CU (CN) L~,,"~ Me2Cu (SCN) Liz," c and M~(~-T~) CU (SCN) ...