Stereoselective Transformation of Baylis-Hillman Adducts into (3E)-3-(Alkoxymethyl) alk-3-en-2-ones

…, RS Hyma, K Muthukumaran, N Kumaragurubaran

文献索引：Basavaiah, Deevi; Suguna Hyma, Rachakonda; Muthukumaran, Kannan; Kumaragurubaran, Nagaswamy Synthesis, 2000 , # 2 p. 217 - 219

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被引用次数: 11

摘要

Abstract: The pure (3E)-3-(methoxymethyl) alk-3-en-2-ones and (3E)-3-(ethoxymethyl) alk-3- en-2-ones are formed in the acid induced reaction of 4-hydroxy-3-methylenealkan-2-ones with methanol and ethanol, respectively. Key words: Baylis− Hillman reaction, stereoselectivity,(3E)-3-(alkoxymethyl) alk-3-en-2-ones, trisubstituted alkenes, alcoholysis