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Amidoselenation of olefins and its utilization for synthesis of allylic amides

…, T Aoai, H Owada, S Uemura, M Okano

文献索引:Toshimitsu, Akio; Aoai, Toshiaki; Owada, Hiroto; Uemura, Sakae; Okano, Masaya Journal of Organic Chemistry, 1981 , vol. 46, # 23 p. 4727 - 4733

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被引用次数: 52

摘要

The reaction of phenylselenyl chloride with olefins in acetonitrile containing trifluoromethanesulfonic acid and water affords P-acetamidoalkyl phenyl selenides in good to excellent yields. This represents the fit example of one-pot amidoselenation of mono-and disubstituted olefins. The reaction can be carried out in benzonitrile, propionitrile, butyronitrile, or ethyl cyanoacetate. It was confirmed that the amidoselenation reaction ...