Radiation Chemistry of N??Hexane Aqueous Solutions as Studied by Chromatographic Analysis of Final Products

J De Doncker, B Tilquin

文献索引：Doncker, J. de; Tilquin, B. Bulletin des Societes Chimiques Belges, 1991 , vol. 100, # 2 p. 107 - 113

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被引用次数: 1

摘要

Abstract Radiolysis of dilute oxygen-free hexane aqueous solutions give dodecanes isomers analyzed by capillary gas chromatography. The relative yields for radicals which react by radical-radical recombination reactions are 39%, 32% and 29% for primary hexyl radical, secondary-2 hexyl radical and secondary-3 hexyl radical respectively. This distribution is changed with the N 2 O saturation before the radiolysis to 22% 42% and 37 ...