α, β-Unsaturated Sulfides. The Reaction of Thiophenol with Certain Ketones1

E Campaigne, JR Leal

文献索引：Campaigne; Leal Journal of the American Chemical Society, 1954 , vol. 76, p. 1272,1274

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被引用次数: 48

摘要

Discussion In order to determine whether the formation of the unsaturated sulfides observed previously'was the result of the unstable nature of the mercaptals initially formed or of the low reactivity of the thiol used, 2-methyl-1-indanone was treated with benzyl mercaptan.* In this case, the nature of the thiol did not appear to be the only factor involved in the formation of the a, P-unsaturated sulfide since benzyl 2-methyl-2-indenyl sulfide was obtained. ...