Tetrahedron letters

New chiral anisotropic reagents, NMR tools to elucidate the absolute configurations of long-chain organic compounds

…, H Takahashi, P Xu, T Fukushima, Y Asakawa…

文献索引：Kusumi, Takenori; Takahashi, Haruko; Xu, Ping; Fukusima, Toshiro; Asakawa, Yoshinori; et al. Tetrahedron Letters, 1994 , vol. 35, # 25 p. 4397 - 4400

全文：HTML全文

被引用次数: 109

摘要

Abstract Modified Mosher's method has been extended by use of 9-anthranylmethoxyacetic acid (9ATMA) and 2-naphthylmethoxynaphthylacetic acid (2NMA) instead of MTPA of the conventional method. Anisotropic effects of these reagents are much greater than that of MTPA, and the reagents have been shown to be useful especially to determine the absolute configurations of the secondary alcohols involved in long-chain compounds.