Studies on the intramolecular cycloaddition reaction of mesoionics derived from the rhodium (II)-catalyzed cyclization of diazoimides

…, DL Hertzog, WR Nadler, MH Osterhout…

文献索引：Padwa, Albert; Hertzog, Donald L.; Nadler, William R.; Osterhout, Martin H.; Price, Alan T. Journal of Organic Chemistry, 1994 , vol. 59, # 6 p. 1418 - 1427

全文：HTML全文

被引用次数: 75

摘要

A series of alkenyl-substituted imides were prepared by treating the appropriate amide with 2, 2, 6-trimethyl-4H-1, 3-dioxen-4-one in xylene at 140 OC to give the N-acetoacylated imides. Exposure of these imides to standard diazo transfer conditions gave the desired diazoimides. The carbenoid intermediate derived by treatment of the diazoimide with rhodium (I1) acetate undergoes ready cyclization onto the neighboring amide carbonyl ...