ACS Catalysis

Mild Hydrosulfenylation of Olefins under Neutral Conditions Using a Defined NHC-Ligated Iron–Sulfur Catalyst

I Alt, P Rohse, B Plietker

文献索引：Alt, Isabel; Rohse, Philipp; Plietker, Bernd ACS Catalysis, 2013 , vol. 3, # 12 p. 3002 - 3005

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被引用次数: 9

摘要

A defined NHC-Fe–S complex proved to be an efficient catalyst for the selective hydrosulfenylation of α, β-unsaturated ketones or vinylnitriles. A wide range of different aliphatic thiols were transferred in this atom-economic reaction into the corresponding thioethers. Mild reaction conditions, equimolar amounts of substrates, low catalyst loadings, and mild reaction conditions are characteristic for this transformation.