Synthesis of a Novel Secondary Dialkylammonium Salt with Three Stations and its Threading Through the Cavity of Two Crown Ethers

…, R Chen, D Han, H Jiang, Q Zhou

文献索引：Shen, Jianfen; Luo, Yan; Chen, Rener; Han, Deman; Jiang, Huajiang; Zhou, Qizhong Letters in Organic Chemistry, 2013 , vol. 10, # 2 p. 100 - 104

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摘要

In this paper, a novel secondary dialkylammonium salt with three stations (G1) was synthesized in 5 steps. 1H NMR was used to study the threading of G1 through the cavity of dibenzo-24-crown-8 (DB24C8) and benzo-21-crown-7 (B21C7). The complexation of G1 and two crown ethers was proved to be slow-exchange systems. This result lays the foundation on the integrative self-sorting organization of G1, DB24C8 and B21C7.