Modeling of vinylidene fluoride heterogeneous polymerization in supercritical carbon dioxide

PA Mueller, G Storti, M Morbidelli, M Apostolo…

文献索引：Mueller, Philipp A.; Storti, Giuseppe; Morbidelli, Massimo; Apostolo, Marco; Martin, Roland Macromolecules, 2005 , vol. 38, # 16 p. 7150 - 7163

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被引用次数: 49

摘要

The heterogeneous polymerization of vinylidene fluoride in supercritical carbon dioxide has been investigated experimentally, and the obtained results have been interpreted through a detailed kinetic model. The comparison between model predictions and experimental data indicates the presence of two reaction loci: the continuous supercritical phase and the dispersed polymer phase. However, the presence of two reaction loci is not the result of ...