Abstract A crown-tetrathiafulvalene electroactive receptor has been covalently linked to electropolymerizable pyrrole or 3, 4-ethylenedioxythiophene monomers. The synthetic route to the monofonctionalized tetrathiafulvalene (TTF) ligand has been optimized. Two derivatives of pyrrole (N-and 3-substituted) were synthesized. The various substituted monomers have been electropolymerized to produce polypyrrole (PP) and poly ( ...