Tetrahedron

Mild and efficient Diels-Alder reaction using cationic dienophiles generated in situ

…, T Nagashima, K Kobayashi, M Hasegawa, K Saigo

文献索引：Hashimoto, Yukihiko; Nagashima, Tadamichi; Kobayashi, Katsuhiro; Hasegawa, Masaki; Saigo, Kazuhiko Tetrahedron, 1993 , vol. 49, # 29 p. 6349 - 6358

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被引用次数: 14

摘要

On the action of a Lewis acid, 2, 2-dimethoxyethyl acrylate is readily transformed into a reactive cationic dienophile, and it reacts with dienes under mild conditions to give Diels- Alder adducts in good yields with high stereo-and/or regioselectivity. 2-Oxopropyl acrylate ...