A boronic acid–diol interaction is useful for chiroselective transcription of the sugar structure to the Δ-versus Λ-[Co III (bpy) 3] 3+ ratio

…, M Takeuchi, I Hamachi, K Nakashima…

文献索引：Mizuno, Toshihisa; Takeuchi, Masayuki; Hamachi, Itaru; Nakashima, Kazuaki; Shinkai, Seiji Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 10 p. 2281 - 2288

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被引用次数: 4

摘要

In order to apply boronic acid–saccharide interactions to the chiroselective synthesis of Δ- and Λ-[Co III (bpy) 3] 3+ saccharide-binding ligands, 2, 2′-bipyridine-4-boronic acid (bpymb) and 2, 2′-bipyridine-4, 4′-diboronic acid (bpydb) were newly synthesized. It was shown that most D-saccharides form cyclic 1∶ 1 complexes with bpydb to afford the CD- active species. The positive exciton coupling band implies that two pyridine rings are ...