Unsymmetrical azo initiators increase efficiency of radical generation in aqueous dispersions, liposomal membranes, and lipoproteins

SM Culbertson, NA Porter

文献索引：Culbertson, Sean M.; Porter, Ned A. Journal of the American Chemical Society, 2000 , vol. 122, # 17 p. 4032 - 4038

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被引用次数: 30

摘要

Lipid peroxidation studies often employ the use of azo initiators to produce a slow, steady source of free radicals, but the lack of initiators capable of efficiently generating radicals in lipid aggregates such as micelles and membranes has created persistent problems in these investigations. We report here the synthesis and study of unsymmetrically substituted (hydrophilic/hydrophobic) azo initiators C-8, C-12, and C-16 that increase the efficiency of ...