Synthesis of conjugated polyrotaxanes

JJ Michels, MJ O'Connell, PN Taylor…

文献索引：Michels, Jasper J.; O'Connell, Michael J.; Taylor, Peter N.; Wilson, Joanne S.; Cacialli, Franco; Anderson, Harry L. Chemistry - A European Journal, 2003 , vol. 9, # 24 p. 6167 - 6176

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被引用次数: 149

摘要

Abstract A series of conjugated polyrotaxane insulated molecular wires are synthesised by aqueous Suzuki polymerisation, using hydrophobic binding to promote threading of the cyclodextrin units. These polyrotaxanes have conjugated polymer cores based on poly (para- phenylene), polyfluorene, and poly (diphenylene-vinylene), threaded through 0.9–1.6 cyclodextrins per repeat unit. Bulky naphthalene-3, 6-disulfonate endgroups prevent the ...