Synlett

Lithium naphthalenide induced reductive selenenylation of α-cyano ketones: A regiocontrolled process for α-phenylseleno ketones and one-pot conversion into enone …

JL Zhu, YC Ko, CW Kuo, KS Shia

文献索引：Zhu, Jia-Liang; Ko, Yen-Chun; Kuo, Chun-Wei; Shia, Kak-Shan Synlett, 2007 , # 8 p. 1274 - 1278

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被引用次数: 10

摘要

Abstract An efficient procedure for the regiocontrolled synthesis of α-phenylseleno ketones has been developed, making use of the lithium naphthalenide induced reductive selenenylation of the α-cyano ketone system as a key operation. Moreover, seleno ketones thus generated in situ, upon subsequent treatment with hydrogen peroxide and acetic acid, could be further converted into the corresponding enones with a high degree of ...