Mechanistic Aspects of Hydrosilylation Catalyzed by (ArN=) Mo (H)(Cl)(PMe3) 3

…, OG Shirobokov, E Peterson, R Simionescu…

文献索引：Khalimon, Andrey Y.; Simionescu, Razvan; Nikonov, Georgii I. Journal of the American Chemical Society, 2011 , vol. 133, # 18 p. 7033 - 7053

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被引用次数: 32

摘要

Until very recently, the main mechanistic proposal for metal catalyzed hydrosilylation had been based on the variations of Chalk–Harrod mechanism(9) (for alkenes and alkynes) and Ojima mechanism (for carbonyls),(10) which starts with oxidative addition of silane to metal, substrate coordination, and migration of the silyl (or the hydride ligand) followed by either reductive C–H elimination (or Si–C for alkenes and O–Si elimination for carbonyls). Heterolytic ...