Generation of 2-Carboethoxyethylzinc iodide and 3-carboethoxypropylzinc iodide and their application to the synthesis of γ-and δ-keto esters

Y Tamaru, H Ochiai, T Nakamura, K Tsubaki…

文献索引：Tamaru, Yoshinao; Ochiai, Hirofumi; Nakamura, Tatsuya; Tsubaki, Kazunori; Yoshida, Zen-ichi Tetrahedron Letters, 1985 , vol. 26, # 45 p. 5559 - 5562

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被引用次数: 109

摘要

Abstract 2-Carboethoxyethylzinc iodide and 3-carboethoxypropylzinc iodide are generated by the reaction of the corresponding iodoesters with Zn-Cu couple and utilized for the palladium catalyzed coupling reaction with acid chloride to quantitatively provide gamma- and delta-keto esters, respectively.