Isolation, structure elucidation, and synthesis of novel hydroxylamine-containing polyamines from the venom of the Agelenopsis aperta spider

…, D Phillips, KJ Rosnack, NA Saccomano…

文献索引：Jasys, V. John; Kelbaugh, Paul B.; Nason, Deane M.; Phillips, Douglas; Rosnack, Kenneth J.; Saccomano, Nicholas A.; Stroh, Justin G.; Volkmann, Robert A. Journal of the American Chemical Society, 1990 , vol. 112, # 18 p. 6696 - 6704

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被引用次数: 97

摘要

Abstract: Novel hydroxylamine-containing polyamines have been isolated from the venom of Agelenopsis aperta, a funnel-web spider found throughout the western United States.'H and" Cnmr in concert with UV spectroscopy provided important structural inputs particularly for determining the aromatic chromophores. Fast-atom bombardment (FAB) mass spectrometry, however, provided the key data for establishing the polyamine functionality of Age1 489 (l) ...