Tetrahedron letters

An expedient stereoselective synthesis of (Z)-and (E)-allyl iodides from Baylis–Hillman adducts along with selective iodination of benzylic alcohols using the …

B Das, H Holla, Y Srinivas, N Chowdhury, BP Bandgar

文献索引：Das, Biswanath; Holla, Harish; Srinivas, Yallamalla; Chowdhury, Nikhil; Bandgar Tetrahedron Letters, 2007 , vol. 48, # 18 p. 3201 - 3204

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被引用次数: 20

摘要

A stereoselective method has been developed for the synthesis of (Z)-and (E)-allyl iodides from Baylis–Hillman adducts using polymethylhydrosiloxane (PMHS) and iodine in chloroform at room temperature. In addition, the reagent system has been utilized for the iodination of benzylic alcohols selectively.