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Applied Catalysis A: General

Silica grafted polyethylenimine as heterogeneous catalyst for condensation reactions

SM Ribeiro, AC Serra, AMAR Gonsalves

文献索引:Ribeiro, Sonia M.; Serra, Armenio. C.; Gonsalves, A.M. D'A. Rocha Applied Catalysis A: General, 2011 , vol. 399, # 1-2 p. 126 - 133

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被引用次数: 15

摘要

Abstract Primary amine groups were attached to a silica surface by using α, ω-diamines derivatives and (3-glycidyloxypropyl)-trimethoxysilane activation. The same activation was used to graft polyethylenimine, which also contains secondary and tertiary amine groups. These silica aminated structures were tested as heterogeneous catalysts in nitroaldol condensation with nitromethane, the derivative with the polyethylenimine moiety being the ...