Cobalt??Catalyzed Reductive Allylation of Alkyl Halides with Allylic Acetates or Carbonates

…, A Auffrant, A Felouat, C Gosmini

文献索引：Qian, Xin; Auffrant, Audrey; Felouat, Abdellah; Gosmini, Corinne Angewandte Chemie - International Edition, 2011 , vol. 50, # 44 p. 10402 - 10405

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被引用次数: 43

摘要

Transition-metal-catalyzed allylic alkylations, using a broad range of metal complexes, have been intensively studied because of their potential applications in the synthesis of new olefinic compounds in particular for total synthesis.[1] Soft nucleophiles are usually used in Pd-,[1] Mo-,[2] Ir-,[3] Ru-,[4] Rh-,[5] Pt-,[6] and even Fe-catalyzed [7] allylic substitutions. Ni,[8] Co,[9] and Cu [10] catalysts allow the use of hard nucleophiles such as alkylzinc or ...