Selective Rhodium (III)??Catalyzed Cross??Dehydrogenative Coupling of Furan and Thiophene Derivatives

N Kuhl, MN Hopkinson, F Glorius

文献索引：Kuhl, Nadine; Hopkinson, Matthew N.; Glorius, Frank Angewandte Chemie - International Edition, 2012 , vol. 51, # 33 p. 8230 - 8234

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被引用次数: 91

摘要

The cross-dehydrogenative coupling (CDC) of two unfunctionalized arenes is one of the most attractive transformations to build up the ubiquitous biaryl motif.[1, 2] In comparison to established cross-coupling reactions between aryl halides and organometallic reagents,[3] CDC is considered a more efficient and environmentally friendly approach since it circumvents the often tedious and wasteful prefunctionalization of starting materials. ...