Tetrahedron

Rational design of Mn-Salen epoxidation catalysts: Preliminary results

N Hosoya, A Hatayama, R Irie, H Sasaki, T Katsuki

文献索引：Hosoya, Naoki; Hatayama, Akira; Irie, Ryo; Sasaki, Hidehiko; Katsuki, Tsutomu Tetrahedron, 1994 , vol. 50, # 15 p. 4311 - 4322

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被引用次数: 118

摘要

(Salen) manganese (III) complex 7 designed on the basis of the new proposal on the olefin's access to metal-oxo bond and complex 10 having axial chirality in salicylaldehyde part were found to be effective catalysts for the epoxidation of unfunctionalized olefins, especially for cis-olefins.