Chemistry–A European Journal

Allene Carboxylates as Dipolarophiles in Rh??Catalyzed Carbonyl Ylide Cycloadditions

L Rout, AM Harned

文献索引：Rout, Laxmidhar; Harned, Andrew M. Chemistry - A European Journal, 2009 , vol. 15, # 47 p. 12926 - 12928

全文：HTML全文

被引用次数: 36

摘要

Foregoing their past as structural oddities and molecules of only fundamental interest, allenes have proven themselves as valuable synthetic building blocks and reaction intermediates.[1] In part, the interest in these molecules stems from their axial chirality,[2] which has tremendous potential in the realm of stereoselective synthesis (Figure 1).[1, 3] We have recently begun a program aimed at utilizing the unique structural features of axially ...