Tetrahedron Letters

Mild and efficient synthesis of thiocarbonates and thiocarbamates via a three-component coupling utilizing Cs 2 CO 3 and TBAI

RN Salvatore, S Sahab, KW Jung

文献索引：Salvatore, Ralph N.; Sahab, Suma; Jung, Kyung Woon Tetrahedron Letters, 2001 , vol. 42, # 11 p. 2055 - 2058

全文：HTML全文

被引用次数: 64

摘要

The presence of cesium carbonate and tetrabutylammonium iodide (TBAI) facilitated efficient thiocarbonylation of alcohols, and thiocarbamation of amines, using carbon disulfide with alkyl halides. This protocol was mild, chemoselective, and efficient, compared to the existing methods.