Boryltrihydroborate: synthesis, structure, and reactivity as a reductant in ionic, organometallic, and radical reactions

K Nozaki, Y Aramaki, M Yamashita…

文献索引：Nozaki, Kyoko; Aramaki, Yoshitaka; Yamashita, Makoto; Ueng, Shau-Hua; Malacria, Max; Lacote, Emmanuel; Curran, Dennis P. Journal of the American Chemical Society, 2010 , vol. 132, # 33 p. 11449 - 11451

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被引用次数: 36

摘要

Reaction of lithium 1, 3-bis (2, 6-diisopropylphenyl)-2, 3-dihydro-1 H-1, 3, 2-diazaborol-2-ide with borane· THF provides the first boryl-substituted borohydride: lithium [1, 3-bis (2, 6- diisopropylphenyl)-2, 3-dihydro-1 H-1, 3, 2-diazaborol-2-yl] trihydroborate. The compound is fully characterized by 11B, 1H, and 7Li NMR spectra and other means, and these data are compared to neutral and anionic benchmark compounds. The compound crystallizes as a ...