Journal of the American Chemical Society

Absence of a common ion effect on the hydrolysis of an. alpha.-azido ether of an aliphatic aldehyde

TL Amyes, WP Jencks

文献索引：Amyes, Tina L.; Jencks, William P. Journal of the American Chemical Society, 1988 , vol. 110, p. 3677 - 3679

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被引用次数: 14

摘要

(Ar= p-MeOC&) acetonitrile under the DCA-sensitized conditions la and lb gave 3ai2 and 3bi2 in 6% and 72% yields, respectively. The yield of 3a was increased to 48% by the addition of Mg (C104) 2.13 If the initial cyclization occurs in a stereospecific manner, its stereochemical integrity should be conserved in the oxygenation product. In order to test this, the direct molecular oxygen trapping of intermediates was further applied for (2, Z)-,(E ...