Carbohydrate research

Improved synthesis and the crystal structure of methyl 4, 6-dideoxy-4-(3-deoxy-L-glycero-tetronamido)-α-D-mannopyranoside, the methyl α-glycoside of the …

M Gotoh, CN Barnes, P Kováč

文献索引：Gotoh, Makoto; Barnes, Charles N.; Kovac, Pavol Carbohydrate Research, 1994 , vol. 260, # 2 p. 203 - 218

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被引用次数: 23

摘要

Abstract The crude product of deamination of the commercially available l-homoserine was acetylated and the 2-O-acetyl-3-deoxy-l-glycero-tetronolactone (18) formed was used to N- acylate methyl perosaminide (methyl 4-amino-4, 6-dideoxy-α-d-mannopyranoside, 12) and its 2, 3-O-isopropylidene derivative. The major product isolated from the reaction was the crystalline methyl 4-(4-O-acetyl-3-deoxy-l-glycero-tetronamido)-4, 6-dideoxy-α-d- ...