Total synthesis of (±)-solavetivone; X-ray crystal structure of 2-hydroxy-6, 10-dimethylspiro [4.5] dec-6-en-8-one

…, T Fusaka, T Fujiwara, K Tomita, M Yamada

文献索引：Iwata, C.; Fusaka, T.; Fujiwara, T.; Tomita, K.; Yamada, M. Journal of the Chemical Society, Chemical Communications, 1981 , # 10 p. 463 - 465

全文：HTML全文

被引用次数: 1

摘要

(Faculty of Pharmaceutical Sciences, Osaka University, 133-1 Yamada-Kami, Suita, Osaka 565, Japan) ... Summary (f)-Solavetivone (1) was synthesized by a new spiro-annelation reaction and a unique regio- and stereo- selective reduction of the spiro-dienone (4) to give (5), the structure of which has been determined by X-ray crystal- lography. ... ( -)-SOLAVETIVONE (1), which has a vetispirane skeleton, has been isolated as a stress metabolite from potato tubers ...