Journal of catalysis

Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C–C coupling of vinylsilanes and halobenzenes leading to styrenes

A Grirrane, H Garcia, A Corma

文献索引：Grirrane, Abdessamad; Garcia, Hermenegildo; Corma, Avelino Journal of Catalysis, 2013 , vol. 302, p. 49 - 57

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被引用次数: 10

摘要

The Hiyama C–C coupling reaction of a wide range of aryl iodides and vinylsilanes has been performed using ligand-free solid catalysts based on supported palladium nanoparticles. Among the supports tested (Mg, TiO2, CeO2 and active carbon), the most active catalysts were those in which palladium is supported on MgO and TiO2. Analogous Pt and Au materials were inefficient to promote this reaction. Leaching tests suggest that ...